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Research Papers

Electrohydrodynamic Casting Bismuth Telluride Microparticle-Loaded Carbon Nanofiber Composite Material With Multiple Sensing Functions

[+] Author and Article Information
Yong X. Gan

Department of Mechanical Engineering,
California State Polytechnic University Pomona,
3801 W Temple Avenue,
Pomona, CA 91768
e-mail: yxgan@cpp.edu

Ann D. Chen, Kevin R. Anderson

Department of Mechanical Engineering,
California State Polytechnic University Pomona,
3801 W Temple Avenue,
Pomona, CA 91768

Jeremy B. Gan

Diamond Bar High School,
21400 Pathfinder Road,
Diamond Bar, CA 91765

1Corresponding author.

Contributed by the Manufacturing Engineering Division of ASME for publication in the JOURNAL OF MICRO- AND NANO-MANUFACTURING. Manuscript received July 19, 2017; final manuscript received October 30, 2017; published online December 14, 2017. Assoc. Editor: Joey Mead.

J. Micro Nano-Manuf 6(1), 011005 (Dec 14, 2017) (9 pages) Paper No: JMNM-17-1043; doi: 10.1115/1.4038432 History: Received July 19, 2017; Revised October 30, 2017

In this work, an electrohydrodynamic casting approach was used to manufacture a carbon nanofiber (CNF) composite material containing bismuth telluride (Bi2Te3) particles. A 10% polyacrylonitrile (PAN) polymer solution was taken as the precursor to generate nanofibers. Bismuth telluride microparticles were added into the polymer solution. The particle-containing solution was electrohydrodynamically cast onto a substrate to form a PAN-based nanofiber composite mat. High temperature heat treatment on the polymeric matrix composite mat in hydrogen atmosphere resulted in the formation of a microparticle-loaded CNF composite material. Scanning electron microscopic (SEM) analysis was conducted to observe the morphology and reveal the composition of the composite material. Energy conversion functions in view of converting heat into electricity, electromagnetic wave energy into heat, and photon energy into electricity were shown. Strong Seebeck effect, hyperthermia, and photovoltaics of the composite mat were found. In addition, the potential applications as sensors were discussed.

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Figures

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Fig. 1

Illustrations showing the electrohydrodynamic manufacturing and the post treatment facilities. (a) Electrohydrodynamic manufacturing system and (b) composite material heat treatment setup: (1) hydrogen gas supply, (2) vacuum pump with pressure gage, (3) stainless steel vacuum sealing flanges, (4) quartz tube, (5) split furnace, (6) porous alumina thermal insulation blacks, (7) Al2O3 substrate, (8) composite sample, (9) cold trap for cooling carrier and released gas, (10) sodium carbonate solution for exhaust gas absorption, (11) hydrogen burning torch, and (12) programmable temperature control unit assembled in the base of the furnace.

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Fig. 2

SEM analysis of the morphology and composition of the partially carbonized composite nanofiber containing Bi–Te microparticles: (a) SEM image of the material at low magnification, (b) SEM image of the composite at a slightly higher magnification, (c) SEM image of the composite at a further higher magnification, (d) SEM image of the composite at an even higher magnification showing the particle and fiber details, and (e) EDS area mapping results

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Fig. 3

Thermoelectric response measurement setup and the results: (a) thermal wave test setup and (b) thermoelectric response of the composite fiber mat showing the general n-type semiconducting behavior

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Fig. 4

Thermoelectric response results showing the feasibility of monitoring breathe-in and breathe-out: (a) short exhaling followed by long inhaling, (b) exhaling and inhaling with equal time, and (c) monitoring the coughing breathe-in and -out patterns

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Fig. 5

Photovoltaic response measurement setup: (a) using the translating steel plate to regulate visible light on the nanofiber specimen and (b) using the fidget spinner to regulate visible light on the nanofiber specimen

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Fig. 6

Time-dependent photoelectric property of the composite nanofiber measured using the translating steel plate to regulate visible light on the nanofiber specimen

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Fig. 7

Photovoltaic responses of the composite tested using the translating steel plate to regulate visible light on the nanofiber specimen: (a) photosensitive response showing the switching behavior, (b) photosensitive response showing the same switching behavior after the composite being kept for 1 month to show the stability of the material, and (c) long time exposure to visible light to show the charge recombination behavior in the composite

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Fig. 8

Photovoltaic response results measured using a fidget spinner to regulate visible light on the nanofiber specimen to demonstrate the sensing function of the composite: (a) photosensitive response of the composite to the light passing through a fidget spinner, (b) photosensitive response showing the same behavior after the composite being kept for 1 month to show the stability of the material, and (c) open circuit voltage decaying pattern used for determining the acceleration of the fidget spinner

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